"RAOULT, F.-M. (FRANCOIS MARIE). - DISCOVERY OF RAOULT'S LAWS.
Reference : 47024
(1882)
(Paris, Gauthier-Villars), 1882. 4to. No wrappers. In: ""Comptes Rendus Hebdomadaires des Séances de L'Academie des Sciences"", Tome 95, No 22 a. Tome 104 No 21 (entire issues offered). Pp. 1017-1076 and pp. 1387-1462. Raoult's papers: pp. 1030-33 (tome 95) and pp. 1430-1433 (tome 104).
First appearance of Raoult's two importent papers in which described a method for finding the molecular weight of an organic compound by the determination of the lowering of the freezing point of water that resulted from dissolving that compound in water and the law governing the relation between solutes and vapor pressure.""Then in 1882, F.-M. Raoult published his results on the effects of nondissociating organic solutes, from which he deduced a general law controlling the lowering of freezing points (the first paper offered). Four years later he extended this work to show the effect of solutes on vapor pressure (the second paper offered). Having established the effect of nondissociating compounds, he was in position to show that salts produced an eeffect which, though anomalous, could nevertheless be explained by the supposition that a dissolved molecule broke up into other molecules. This work was of great value in supplying a new method for determining molecular weights, since the depression of freezing point and vapor pressure (as well a the related rise in boiling point later discovered) are proportional to the moleculat concentrations ofthe solutions"" it was of equal value in supporting the ideas of van't Hoff on osmotic pressure. With the announcement of the dissociation theory of Arrhenius, the anomalies were explained and the full significance of the generalizations of Raoult was recognized. Raoult published the formulations of his laws in the ""Comptes Rendus"" for 1882 and 1887 (the papers offered)"" (Leicester a. Klickstein ""A Source Book in Chemistry"", pp. 471 ff).
Paris, G. Masson, 1886. Bound with the original printed wrappers to all 4 issues (8 wrappers) in contemp. hcalf. Wear to top of spine. Light wear along edges. Two small stamps on verso of titlepage. In ""Annales de Chimie et de Physique"", 6. Series - Tome VIII. 576 pp. and 1 folded engraved plate. The entire volume offered. Raoult's paper: pp. 317-339.
First printing. In a brilliant paper in 1886, Raoult derived an expression for the relative lowering of the vapor pressure of solutions in ether, which is still in use.Also containing another paper by Raoult ""Influence du Degré de Concentration sur le Poilt de Congélation des Dissolutions"", pp. 289-317.
Paris, Victor Masson et Fils, Imprimerie Gauthier-Villars, 1864-65. 8vo. Bound in 2 contemp. hcalf, raised bands, gilt spine. Light wear along edges, spines slightly rubbed.. Small stamps on verso of titlepage. In ""Annales de Chimie et de Physique"", 4e Series - Tome 2 a. 4. 512 pp. and 2 folded engraved plates. + 512 pp. and 3 folded engraved plates. (The entire volumes offered). Raoult's papers: pp. 317-372 a. pp. 392-426.
First printing of these pioneering papers in thermochemistry and electrochemistry.""Raoult’s work may be divided into three stages: physical, chemical, and physicochemical. During the first stage, which lasted until Raoult moved to Grenoble, he discovered that the chemical heat of reaction of galvanic cells of the Daniell type was generally different from the heat equivalent of the electrical work done in these cells. He also used a voltameter, an instrument that measures the quantity of electricity by the amount of electrolysis, to study the heat evolved in voltaic cells. Raoult was one of the first to recognize that the electrical work done by voltaic cells was not equal to the heat evolved by the chemical reaction driving these cells. He showed that whenever the electrical work done in voltaic cells was less than the heat of all reactions, heat was evolved. Moreover, he stated that changes in concentration, oxidation, and in acid-base relationships, but not changes in aggregation such as dissolving, melting, or solidifying, were the sources of the electromotive force of voltaic cells.""(DSB).
Paris, G. Masson, 1890. Contemp. hcalf. Light wear along edges. Two small stamps on verso of titlepage. In ""Annales de Chimie et de Physique"", 6. Series - Tome XX. 576 pp. The entire volume offered. Raoult's paper: pp. 297-371. Clean and fine.
First printing of an importent paper in which Raoult gives further applications of his own discovery, ""Raoult's Law""""Raoult soon turned to the anomalous results with salts in water, which had puzzled previous investigators. He classified the salts he used according to the valence of the radicals and found that the lowering of the freezing point could be accounted for by assigning certain numbers to these radicals. He demonstrated that the freezing point lowering obtained with these salts was consistent with the hypothesis that the salt radicals themselves acted as if they existed independently in the solution, and that certain radicals were more effective than others in lowering the freezing point of water. With the statement that ""the neutral salts of mono and di-basic salts act as if the electropositive and electronegative radicals of these salts when dissolved in water solution do not combine, but remain as simple mixtures (in the paper offered), Raoult showed that he had come to accept much of Arrhenius’ work on ionization.""(DSB).
Paris, G. Masson, 1888. Contemp. hcalf. Light wear along edges. Two small stamps on verso of titlepage. In ""Annales de Chimie et de Physique"", 6. Series - Tome XV. 576 pp. and 2 folded engraved plates. The entire volume offered. Raoult's paper: pp. 375-407. lean and fine.
First printing of an importent paper in which Raoult gives further applications of his own discovery, ""Raoult's Law""
J. B. Baillière 1833 In-8, demi-basane peignée, dos lisse, filets, fleuron et dentelles dorées, 96- 576 pages, 12 planches dépliantes, avec quelques figures coloriées à la main, 1 tableau dépliant. Menus frottements, rares rousseurs. "Cette première édition parue en 1833 en un volume, fut traduite dans toutes les langues européennes et nul n'ignore que cet ouvrage imprima une impulsion toute nouvelle à la chimie organique et y opéra une complète révolution" Catalogue raisonné des ouvrages de M. Raspail
Bon état d’occasion
J.-B. Baillière. 1838. In-8. Broché. Bon état, Plats abîmés, Coiffe en pied abîmée, Non coupé. 685 pages. 20 planches de figures gravées. Déchirure sur le 2ème plat. Tranches irrégulières. Nombreuses rousseurs.. . . . Classification Dewey : 540-Chimie et sciences connexes
Classification Dewey : 540-Chimie et sciences connexes
1833 demi- rel. époque. in-8, 96pp., 1 tableau, 576pp., 12 pl. repl. dont 6 coloriées, Paris Baillière 1833.
E.O. Raspail est considéré comme le créateur de la chimie organique. Belle dédicace " A la mémoire d'un homme de bien, mon pauvre maître, l'Abbé Eysséric " datée de la maison d'arrêt de Versailles." Raspail held a prominent place in the development of sciences in the 19th century. In organic chemlstry he specified the properties of numerous substances... Raspail belonged to a group of biologist who prepared the way for the rise of the cell theory. Although it would be too strong to call him the creator of the modern concept of the cell... " (D.S.B.)."This book was important as the first work in which the microscope was successfully employed in organic chemistry" (Duveen).
Paris Hermann et Cie 1936 In-12 182 pp, 2ème édition. Exemplaire non coupé, figures en noir in et hors-texte. Faibles mouillures au dos et au bord de la 1ère de couv.
Bon Broché à raba
Genève, Taponnier, 1894, gr. in-8vo, 47 p., brochure originale.
Phone number : 41 (0)26 3223808
Stuttgart, Georg Thieme, 1964, in-4to, XXIII + 469 S., reich ill. mit Abb., Vorsatz gestempelt, eingeklebte Ausleihkarte an Innendeckel, Original-Leinenband (Bibl.).
Phone number : 41 (0)26 3223808
Bochum, 1987 222 + [67] pp., 30cm., text in English, Doctoral Dissertation ("Dissertation zur Erlangung des Grades 'Doktor der Naturwissenschaften' an der Abteilung für Geowissenschaften der Ruhr-Universität Bochum"), softcover, stamp at verso of title page, text is clean and bright, good condition, weight: 1.1kg., W113238
BAILLIERE J.B. & FILS.. 1966. In-8. Broché. Bon état, Couv. défraîchie, Dos satisfaisant, Intérieur frais. 370 pages. Nombreuses figures en noir et blanc dans le texte.. . . . Classification Dewey : 540-Chimie et sciences connexes
"Classes de Mathématiques Supérieures et Spéciales. Collection de ""Sciences Physiques."", de Marcel Peschard Classification Dewey : 540-Chimie et sciences connexes"
Editions CNRS 1998 379 pages Paris. in-8. 1998. Broché. 379 pages.
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"RAYLEIGH, LORD (J.W. STRUTT) and WILLIAM RAMSAY. - THE DISCOVERY OF ARGON.
Reference : 49207
(1895)
London, Harrison and Sons, 1895. 4to. Orig. full cloth. Gilt lettering to spine. Blindtooled covers. First corner a bit bumped. In ""Philosophical Transactions"", Vol. 186 - I, Series A. XIV,(2),602,(4) pp. (Entire volume offered). The paper: p. 187-241 a. 8 textillustrations (apparatus). The title-page with faint brownspots. Otherwise internally clean and fine.
First printing of this importent paper in the history of chemistry, Lord Rayleigh's most famous discovery, announcing the discovery of this new gas, the first finding of one of the rare gases (inert gases) having unusual properties, and forming a distinct group in the periodic table, and all with zero valency.""The original paper in the ""Philosophical Transactions"" will undoubtly rank as a classic, the investigation having been a particularly brilliant ine."" (Ernst von Meyer in History of Chemistry). For this discovery Lord Rayleigh and W. Ramsay received the Nobel Prize (1904). The volume also contains WILLIAM CROOKES ""On the Spectra of Argon"", OSBORNE REYNOLD ""On the Dynamical Theory of Incompressible Viscous Fluids and the determination of the Criterion"", KARL PEARSON ""Contributions to the Mathematical Theory of Evolution. - II. Skew Variations in Homogenous Materials"" etc.After having made several measuring of the densities of gases, ""Rayleigh came across a curious puzzle. With oxygen, he always obtained the same density, regardless of how the oxygen might be produced, whether from one particular compound, from a second compound, or from the air. The situation was different with nitrogen. The nitrogen he obtained from air constantly showed a slightly higher density than the nitrogen he obtained from any of various compounds. Rayleigh could think of several ways in which the nitrogen obtained from air might be contaminated but none of the possibilities checked out experimentally. He was so frustrated that he went so far as to write to the journal ""Nature"" asking for suggestions. Ramsay, a brilliant Scottish chemist, asked permission to tackle the problem and received it. The upshot was that a new gas, somewhat denser that nitrogen, was discovered to exist in the atmosphere. It was named argon and it was the first of a series of rare gases of unusual properties whose existence had never been suspected.""(Asimow).Dibner, Heralds of Science No. 50 - Neville, Historical Chemical Library vol. II, p.358.
P., I.N.S., (1949), in 8° broché, 367pp., 50 figures et 22 tableaux.
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Institut National de Sécurité Institut National de Sécurité pour la Prévention 1962. In-8 broché de 417 pages. Photos. Légères rousseurs en bord de couverture sinon Bon état
Toutes les expéditions sont faites en suivi au-dessus de 25 euros. Expédition quotidienne pour les envois simples, suivis, recommandés ou Colissimo.
Ioannina, Université de Jannina, 1989. In-8 broché, 256 pp., fig. en n/b. in-t., appendices, bibliographie, index. Envoi manuscrit de l'auteur au professeur Jehan Desanges.
Collection : "Dodoné" Parartema, 29. Bon ex. - Frais de port : -France 6,8 € -U.E. 9 € -Monde (z B : 14 €) (z C : 24 €)
- FACULTE DE MEDECINE ET DE PHARMACIE DE BORDEAUX. NON DATE. In-4. Broché. Etat d'usage, Couv. défraîchie, Dos satisfaisant, Intérieur acceptable. 190 pages - nombreuses pages désolidarisées - quelques figures en noir et blanc dans le texte.. . . . Classification Dewey : 540-Chimie et sciences connexes
Classification Dewey : 540-Chimie et sciences connexes
DUNOD 1965 in8. 1965. Broché.
Très bon état bonne tenue intériuer propre
FACULTE DE PHARMACIE DE BORDEAUX. 1941. In-4. Broché. Etat d'usage, Couv. légèrement passée, Dos satisfaisant, Rousseurs. 11 pages. Ouvrage dactylographié.. . . . Classification Dewey : 540-Chimie et sciences connexes
Classification Dewey : 540-Chimie et sciences connexes
Dunod. 1967. In-12. Broché. Bon état, Couv. convenable, Dos satisfaisant, Intérieur frais. XIII + 170 pages - quelques figures en noir et blanc dans le texte.. . . . Classification Dewey : 540-Chimie et sciences connexes
Collection monographies dunod - traduit par G.Chapas. Classification Dewey : 540-Chimie et sciences connexes
Couverture souple. 8 revues d'environ 40 pages, une revue de 200 pages. Petit manque à la couverture du N° 245.
Périodique. Le numéro spécial 249 de juin 1935 est consacré au compte rendu du deuxième congrès national de la peinture et des industries qui s'y rattachent. Office national des recherches et inventions, 1935.
,Tunis, Imprimerie Centrale administrative 1926, 6 pp., 1 vol. in 8 br. Publication du Laboratoire de Chimie des Services administratifs et de la Répression des Fraudes de la Régence . Tableau dépliant
Paris GARNIER Frères, Vicor MASSON 1859 quatre volumes in-12°, 428, 413, 466 et 582 pp. Reliure ancienne en demi-veau blond, dos à nerfs, soulignés de filets dorés, ornés de pièces de titre et de tomaison en maroquin rouge, gardes marbrées. (dos très légèrement tâchés, présence de faibles rousseurs). Ouvrage orné de 689 figures dans le texte et de quelques planches hors-texte. Bel exemplaire.
5ème Édition